CHAPTER(3) – Coordination chemistry
Artist’s Colour Wheel
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The observed color of a compound from the color of
Limitations of Crystal Field Theory
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Crystal Field Theory was given by Hans Bethe and Van
Evidence of metal-ligand covalent bonding in complexes
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1.Cr(CO)6 is a volatile compound and Ni(CO)4 is a liquid.
Application of CFSE
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1.Enthalpy of Hydration: When one mole of an ionic crystal is
Pairing Energy
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Pairing Energy:         The energy required to force
Factors Affecting the magnitude of ∆
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There are several factors that affect the magnitude of splitting
Splitting of d-orbital in octahedral complex
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Crystal field splitting in Octahedral complex: In a free metal cation
Crystal Field Theory
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Crystal Field Theory:          Valence bond theory
Hybridisation in outer orbital octahedral complex
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Outer orbital octahedral complex:        Let's take an
Inner orbital octahedral complex
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Let's discuss inner orbital complexing taking an example, [Co(CN)6]3-  ionIn this
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