CHAPTER(1) – Chemical Equilibrium
langmuir isotherm
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Langmuir Adsorption Isotherm In 1916 Langmuir proposed his theory which said
Concept of free energy
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Free energy is a thermodynamic function like enthalpy and entropy.It
Le-Chatelier’s principle
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Le-Chatelier's principle:This is based on the fundamental of a stable
Thermodynamics of equilibrium
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Reaction Quotient(Q):         At each point in a reaction ,we can
Important relationship involving equilibrium constant
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1. If we reverse an equation  KP or  KC  is reversed.           If              A
Relationship between Kp ,Kc, Kx and Kn
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Kp=Equilibrium constant in terms of partial pressure.Kc=Equilibrium constant in terms
Equilibrium constant in terms of partial pressure.
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 Both KP and Kc  are equilibrium constants,but  Kc  is defined by molar concentration    but  KP is
Law of mass action/Law of chemical equilibrium
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Principle of Chemical equilibrium:This theory was proposed by Goldberg and
CHEMICAL EQUILIBRIUM
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EQUILIBRIUM:Equilibrium is a state of reversible reaction in which rate